Product ID:LPGAS PROPANE W/ODORANT
MSDS Date:04/10/1986
FSC:6830
NIIN:00-261-7446
MSDS Number: BKYJY

EXXON COMPANY USA

HOUSTON, TX 77252-2180

Emergency Phone: (713) 656-5949 656-2443

Info Phone: (713) 656-5949 656-2443

Cage: DO849

EXXON COMPANY USA

2180 HOUSTON, TX 77252-2180 US

Telephone: 713-656-5949; 800-298-4007

Cage: DO849

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

ODORANT

LD50 LC50 Mixture:ORAL LD50 (RAT): >5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: ASPHYXIATION. SKIN:
FROSTBITE, REMOVE OILS, IRRITATION, & DERMATITIS. EYES: IRRITATION.
INGESTION: HARMFUL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: ASPHYXIATION. SKIN: FROSTBITE,
REMOVE OILS, IRRITATION, & DERMATITIS. EYES: IRRITATION. INGESTION:
HARMFUL.

First Aid:SKIN: TREAT FOR FROSTBITE. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR OR OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING.
EYES: OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:TCC
Flash Point:<0F
Lower Limits:2.1%
Upper Limits:9.5%
Extinguishing Media:FOLLOW THE NFPA, FIRE PROTECTION GUIDE ON HAZARDOUS
MATERIALS.
Fire Fighting Procedures:STOP FLOW OF GAS. USE WATER TO KEEP
FIRE-EXPOSED CONTAINERS COOL/PROTECT PERSONNEL. USE WATER SPRAY TO
DISPERSE GAS/VAPOR. USE SCBA IN ENCLOSED/CONFINED AREAS.
Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 842F. FLAMMABLE
LIQUID.

Spill Release Procedures:SHUT OFF & ELIMINATE IGNITION SOURCES.
EVACUATE AREA. VENTILATE CONFINED SPACES. OPEN ALL WINDOWS & DOORS.

Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/PILOT
LIGHTS/STATIC ELECTRICITY/OPEN FLAME/KEEP CLOSED WHEN NOT IN USE.
AVOID BREATHING GASESVAPORS/FUMES & CONTACT W/SKIN.
Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE/BE DANGEROUS. DON'T
PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND, MAY EXPLODE/CAUSE
INJURY/DEATH. WORK ON TANKS REFER TO OSHA/GOVT/INDUSTRIAL
REFERENCES FOR CLEANING/RE PAIRING/WELDING/CONTEMPLATED OPERATIONS.

Respiratory Protection:USE SUPPLIED-AIR RESPIRATOR IN CONFINED OR
ENCLOSED AREAS.
Ventilation:USE SUFFICIENT VENTILATION TO KEEP EXPLOSIVE CONCENTRATIONS OF VAPOR IN AIR. EXPLOSION-PROOF EQUIP.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GLASSES
Other Protective Equipment:CHEMICAL RESISTANT APRON OR OTHER CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES
BEFORE REUSE. WASH AFTER CONTACT/BEFORE BREAKS/MEALS/END OF DAY. NO
SMOKING.
Supplemental Safety and Health

Boiling Pt:B.P. Text: -49 TO 32F
Vapor Pres: 208 PSIG
Vapor Density:1.5
Spec Gravity:0.50
pH: 7
Solubility in Water:NEGLIGIBLE
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS SUCH AS LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM OR
CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:HEAT, FLAME, SPARKS, PILOT LIGHTS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:FUMES, SMOKE, CO, ALDEHYDES, & OTHER
PRODUCTS OF INCOMPLETE COMBUSTION.

Waste Disposal Methods:HIGH VOLATILITY OF MATERIAL WILL CAUSE EXTREMELY
RAPID EVAPORATION, NO DISPOSAL METHOD IS NEEDED OR SHOULD BE
ATTEMPTED. CONTAINERS SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY
MANNER IN ACCORDANCE W/L OCAL/STATE/FED REGS. FLAMMABLE LIQUID.
UN1075.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.